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Since both sets of mole fractions must sum to unity, xi = yi = 1 Thus, if we sum Eq (1016) over all species and subtract unity from this sum, the difference F, must be zero:

Similar treatment of Eq (1416) yields the difference F,, which must also be zero:

offensive assistant to Jim Lee Howell By this time, Lombardi felt that he had a lot to contribute to a football team s success, and at the Giants summer training camp in 1954 he introduced his ideas to some skeptical pros Eventually, both sides met in the middle, for the benefit of all Lombardi learned how to work with very gifted professional athletes, and the athletes were reintroduced to discipline and hard work Howell had the benefit of two extraordinary assistants: my father on offense and player coach Tom Landry on defense Both went on to lead professional teams to great successes my father at Green Bay and Landry at Dallas They turned the Giants into winners, and other teams took notice In 1957, the Philadelphia Eagles asked my father to take their head coaching position It was tempting: After all, there were only 12 such jobs in the world, and the other 11 were spoken for But the Eagles were in disarray not only on the field, but off the field as well After much agonizing, he turned the Eagles down, hoping for an opportunity with a team with a better management structure That opportunity came at the end of 1958, when one of the worst franchises in the NFL, the lowly Green Bay Packers, asked Lombardi to take over as their head coach The once-proud Packers had just finished a miserable 1 10 1 season, the worst in the team s history Lombardi knew he was in a strong bargaining position, and he took full advantage of that knowledge He signed on as coach and general manager, which effectively gave him complete operating control over the team Most people with any knowledge of football know what happened over the course of the next decade, and I ve already mentioned those remarkable events in the introduction to this book I ll have a lot to say in subsequent chapters about how Lombardi accomplished these feats and what leadership lessons we should draw from those accomplishments.

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4 ~ Gmehling, U Onken, and W Arlt, Vapor-Liquid Equilibrium Data Collection, Chemistry Data Series, vol I, parts 1-8, DECHEMA, FrankfurtMain, 197771990,

where n is the number of moles of gas and b is a different constant for each gas The larger the gas particles, the more volume they occupy and the larger the b value The attraction of the gas particles for each other tends to lessen the pressure of the gas, because the attraction slightly reduces the force of gas particle collisions with the container walls The amount of attraction depends on the concentration of gas particles and the magnitude of the particles intermolecular force The greater the intermolecular forces of the gas, the higher the attraction is, and the less the real pressure Van der Waals compensated for the attractive force with: 2 2 corrected pressure = P + an /V where a is a constant for individual gases The greater the attractive force between the mol2 2 ecules, the larger the value of a The n /V term corrects for the concentration Substituting these corrections into the ideal gas equation gives van der Waals equation: 2 2 (P + an /V )(V nb) = nRT The larger, more concentrated, and stronger the intermolecular forces of the gas, the more deviation from the ideal gas equation one can expect and the more useful the van der Waals equation becomes

Solution to a P , T-flash problem is accomplished when a value of V is found that makes either , function Fy or F equal to zero However, a more convenient function for use in a general solution procedure5is the difference F - F = F : , ,

The advantage of this function is apparent from its derivative:

My father s professional life was devoted mainly to making his teams successful (He didn t tolerate outside interests interfering

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